Condensation of helium in nanoscopic alkali wedges at zero temperature
We present a complete calculation of the structure of liquid He4 confined to a concave nanoscopic wedge, as a function of the opening angle of the walls. This is achieved within a finite-range density functional formalism. The results here presented, restricted to alkali metal substrates, illustrate...
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paper:paper_10980121_v73_n24_p_Hernandez2023-06-08T16:07:33Z Condensation of helium in nanoscopic alkali wedges at zero temperature Hernández, Ester Susana We present a complete calculation of the structure of liquid He4 confined to a concave nanoscopic wedge, as a function of the opening angle of the walls. This is achieved within a finite-range density functional formalism. The results here presented, restricted to alkali metal substrates, illustrate the change in meniscus shape from rather broad to narrow wedges on weak and strong alkali adsorbers, and we relate this change to the wetting behavior of helium on the corresponding planar substrate. As the wedge angle is varied, we find a sequence of stable states that, in the case of cesium, undergo one filling and one emptying transition at large and small openings, respectively. A computationally unambiguous criterion to determine the contact angle of He4 on cesium is also proposed. © 2006 The American Physical Society. Fil:Hernández, E.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10980121_v73_n24_p_Hernandez http://hdl.handle.net/20.500.12110/paper_10980121_v73_n24_p_Hernandez |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
We present a complete calculation of the structure of liquid He4 confined to a concave nanoscopic wedge, as a function of the opening angle of the walls. This is achieved within a finite-range density functional formalism. The results here presented, restricted to alkali metal substrates, illustrate the change in meniscus shape from rather broad to narrow wedges on weak and strong alkali adsorbers, and we relate this change to the wetting behavior of helium on the corresponding planar substrate. As the wedge angle is varied, we find a sequence of stable states that, in the case of cesium, undergo one filling and one emptying transition at large and small openings, respectively. A computationally unambiguous criterion to determine the contact angle of He4 on cesium is also proposed. © 2006 The American Physical Society. |
author |
Hernández, Ester Susana |
spellingShingle |
Hernández, Ester Susana Condensation of helium in nanoscopic alkali wedges at zero temperature |
author_facet |
Hernández, Ester Susana |
author_sort |
Hernández, Ester Susana |
title |
Condensation of helium in nanoscopic alkali wedges at zero temperature |
title_short |
Condensation of helium in nanoscopic alkali wedges at zero temperature |
title_full |
Condensation of helium in nanoscopic alkali wedges at zero temperature |
title_fullStr |
Condensation of helium in nanoscopic alkali wedges at zero temperature |
title_full_unstemmed |
Condensation of helium in nanoscopic alkali wedges at zero temperature |
title_sort |
condensation of helium in nanoscopic alkali wedges at zero temperature |
publishDate |
2006 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10980121_v73_n24_p_Hernandez http://hdl.handle.net/20.500.12110/paper_10980121_v73_n24_p_Hernandez |
work_keys_str_mv |
AT hernandezestersusana condensationofheliuminnanoscopicalkaliwedgesatzerotemperature |
_version_ |
1768541907283083264 |