Photochemical reaction of harmalol. Part 2. Electronic spectra

Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media o...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Biondic, Miriana Carla, Erra Balsells, Rosa
Publicado: 1993
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n5_p887_Biondic
http://hdl.handle.net/20.500.12110/paper_1472779X_v_n5_p887_Biondic
Aporte de:
id paper:paper_1472779X_v_n5_p887_Biondic
record_format dspace
spelling paper:paper_1472779X_v_n5_p887_Biondic2023-06-08T16:17:28Z Photochemical reaction of harmalol. Part 2. Electronic spectra Biondic, Miriana Carla Erra Balsells, Rosa Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media on the electronic spectra and on the prototropic equilibria in the ground and excited singlet states are discussed briefly, as well as those owing to the presence of acidic and basic impurities in the organic media on the electronic spectra. Harmol was selected to be used as a model compound. Emission and excitation spectra of both alkaloids in an adsorbed phase and in the solid state are also described. Fil:Biondic, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1993 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n5_p887_Biondic http://hdl.handle.net/20.500.12110/paper_1472779X_v_n5_p887_Biondic
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media on the electronic spectra and on the prototropic equilibria in the ground and excited singlet states are discussed briefly, as well as those owing to the presence of acidic and basic impurities in the organic media on the electronic spectra. Harmol was selected to be used as a model compound. Emission and excitation spectra of both alkaloids in an adsorbed phase and in the solid state are also described.
author Biondic, Miriana Carla
Erra Balsells, Rosa
spellingShingle Biondic, Miriana Carla
Erra Balsells, Rosa
Photochemical reaction of harmalol. Part 2. Electronic spectra
author_facet Biondic, Miriana Carla
Erra Balsells, Rosa
author_sort Biondic, Miriana Carla
title Photochemical reaction of harmalol. Part 2. Electronic spectra
title_short Photochemical reaction of harmalol. Part 2. Electronic spectra
title_full Photochemical reaction of harmalol. Part 2. Electronic spectra
title_fullStr Photochemical reaction of harmalol. Part 2. Electronic spectra
title_full_unstemmed Photochemical reaction of harmalol. Part 2. Electronic spectra
title_sort photochemical reaction of harmalol. part 2. electronic spectra
publishDate 1993
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n5_p887_Biondic
http://hdl.handle.net/20.500.12110/paper_1472779X_v_n5_p887_Biondic
work_keys_str_mv AT biondicmirianacarla photochemicalreactionofharmalolpart2electronicspectra
AT errabalsellsrosa photochemicalreactionofharmalolpart2electronicspectra
_version_ 1768543624607301632