Photochemical reaction of harmalol. Part 2. Electronic spectra
Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media o...
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1993
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paper:paper_1472779X_v_n5_p887_Biondic2023-06-08T16:17:28Z Photochemical reaction of harmalol. Part 2. Electronic spectra Biondic, Miriana Carla Erra Balsells, Rosa Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media on the electronic spectra and on the prototropic equilibria in the ground and excited singlet states are discussed briefly, as well as those owing to the presence of acidic and basic impurities in the organic media on the electronic spectra. Harmol was selected to be used as a model compound. Emission and excitation spectra of both alkaloids in an adsorbed phase and in the solid state are also described. Fil:Biondic, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1993 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n5_p887_Biondic http://hdl.handle.net/20.500.12110/paper_1472779X_v_n5_p887_Biondic |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
Electronic spectra (absorption, emission and excitation fluorescence spectra) of harmalol in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media on the electronic spectra and on the prototropic equilibria in the ground and excited singlet states are discussed briefly, as well as those owing to the presence of acidic and basic impurities in the organic media on the electronic spectra. Harmol was selected to be used as a model compound. Emission and excitation spectra of both alkaloids in an adsorbed phase and in the solid state are also described. |
author |
Biondic, Miriana Carla Erra Balsells, Rosa |
spellingShingle |
Biondic, Miriana Carla Erra Balsells, Rosa Photochemical reaction of harmalol. Part 2. Electronic spectra |
author_facet |
Biondic, Miriana Carla Erra Balsells, Rosa |
author_sort |
Biondic, Miriana Carla |
title |
Photochemical reaction of harmalol. Part 2. Electronic spectra |
title_short |
Photochemical reaction of harmalol. Part 2. Electronic spectra |
title_full |
Photochemical reaction of harmalol. Part 2. Electronic spectra |
title_fullStr |
Photochemical reaction of harmalol. Part 2. Electronic spectra |
title_full_unstemmed |
Photochemical reaction of harmalol. Part 2. Electronic spectra |
title_sort |
photochemical reaction of harmalol. part 2. electronic spectra |
publishDate |
1993 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n5_p887_Biondic http://hdl.handle.net/20.500.12110/paper_1472779X_v_n5_p887_Biondic |
work_keys_str_mv |
AT biondicmirianacarla photochemicalreactionofharmalolpart2electronicspectra AT errabalsellsrosa photochemicalreactionofharmalolpart2electronicspectra |
_version_ |
1768543624607301632 |