Functionalization of ordered iron-based nanoparticles deposited on mesoporous films

Mesoporous films obtained by dip-coating, combining polycondensation of silicate species and organization of amphiphilic mesophases, were decorated with iron-based nanoparticles from iron aqueous solution. High-resolution transmission electron microscopy (HR-TEM) images and energy dispersive X-rays...

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Autores principales: Marchi, María Claudia, Alvarez, Fernando
Publicado: 2008
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15334880_v8_n1_p448_ClaudiaMarchi
http://hdl.handle.net/20.500.12110/paper_15334880_v8_n1_p448_ClaudiaMarchi
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spelling paper:paper_15334880_v8_n1_p448_ClaudiaMarchi2023-06-08T16:19:58Z Functionalization of ordered iron-based nanoparticles deposited on mesoporous films Marchi, María Claudia Alvarez, Fernando Functionalization Iron particles Mesoporous films Ordered nanoparticles Amphiphilic mesophases Mesoporous films Mesoporous materials Nanostructured materials Polycondensation Transmission electron microscopy X ray photoelectron spectroscopy Nanoparticles Mesoporous films obtained by dip-coating, combining polycondensation of silicate species and organization of amphiphilic mesophases, were decorated with iron-based nanoparticles from iron aqueous solution. High-resolution transmission electron microscopy (HR-TEM) images and energy dispersive X-rays spectroscopy (EDS) analysis show that the nanoparticles have diameters between 5 to 10 nm and they are deposited in an ordered sequence exclusively on top of the mesoporous structure. Afterward, by irradiating the material with a hydrogen ion beam, the iron-based compound is functionalized, i.e., its physical-chemical properties are modified. X-ray photoelectron spectroscopy (XPS) showed that the iron oxides and hydroxides are reduced to metallic iron. The deposition of organized iron-based nanoparticles and further ion beam functionalization might open perspectives on the study and fabrication of complex new materials. Copyright © 2008 American Scientific Publishers All rights reserved. Fil:Claudia Marchi, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Alvarez, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15334880_v8_n1_p448_ClaudiaMarchi http://hdl.handle.net/20.500.12110/paper_15334880_v8_n1_p448_ClaudiaMarchi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Functionalization
Iron particles
Mesoporous films
Ordered nanoparticles
Amphiphilic mesophases
Mesoporous films
Mesoporous materials
Nanostructured materials
Polycondensation
Transmission electron microscopy
X ray photoelectron spectroscopy
Nanoparticles
spellingShingle Functionalization
Iron particles
Mesoporous films
Ordered nanoparticles
Amphiphilic mesophases
Mesoporous films
Mesoporous materials
Nanostructured materials
Polycondensation
Transmission electron microscopy
X ray photoelectron spectroscopy
Nanoparticles
Marchi, María Claudia
Alvarez, Fernando
Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
topic_facet Functionalization
Iron particles
Mesoporous films
Ordered nanoparticles
Amphiphilic mesophases
Mesoporous films
Mesoporous materials
Nanostructured materials
Polycondensation
Transmission electron microscopy
X ray photoelectron spectroscopy
Nanoparticles
description Mesoporous films obtained by dip-coating, combining polycondensation of silicate species and organization of amphiphilic mesophases, were decorated with iron-based nanoparticles from iron aqueous solution. High-resolution transmission electron microscopy (HR-TEM) images and energy dispersive X-rays spectroscopy (EDS) analysis show that the nanoparticles have diameters between 5 to 10 nm and they are deposited in an ordered sequence exclusively on top of the mesoporous structure. Afterward, by irradiating the material with a hydrogen ion beam, the iron-based compound is functionalized, i.e., its physical-chemical properties are modified. X-ray photoelectron spectroscopy (XPS) showed that the iron oxides and hydroxides are reduced to metallic iron. The deposition of organized iron-based nanoparticles and further ion beam functionalization might open perspectives on the study and fabrication of complex new materials. Copyright © 2008 American Scientific Publishers All rights reserved.
author Marchi, María Claudia
Alvarez, Fernando
author_facet Marchi, María Claudia
Alvarez, Fernando
author_sort Marchi, María Claudia
title Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
title_short Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
title_full Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
title_fullStr Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
title_full_unstemmed Functionalization of ordered iron-based nanoparticles deposited on mesoporous films
title_sort functionalization of ordered iron-based nanoparticles deposited on mesoporous films
publishDate 2008
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15334880_v8_n1_p448_ClaudiaMarchi
http://hdl.handle.net/20.500.12110/paper_15334880_v8_n1_p448_ClaudiaMarchi
work_keys_str_mv AT marchimariaclaudia functionalizationoforderedironbasednanoparticlesdepositedonmesoporousfilms
AT alvarezfernando functionalizationoforderedironbasednanoparticlesdepositedonmesoporousfilms
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