Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all t...
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1999
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec |
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paperaa:paper_01082701_v55_n6_p858_Perec2023-06-12T16:46:33Z Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate Acta Crystallogr Sect C Cryst Struct Commun 1999;55(6):858-860 Perec, M. Baggio, R. Garland, M.T. The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1999 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
language |
Inglés |
orig_language_str_mv |
eng |
description |
The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography. |
format |
Artículo Artículo publishedVersion |
author |
Perec, M. Baggio, R. Garland, M.T. |
spellingShingle |
Perec, M. Baggio, R. Garland, M.T. Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
author_facet |
Perec, M. Baggio, R. Garland, M.T. |
author_sort |
Perec, M. |
title |
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
title_short |
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
title_full |
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
title_fullStr |
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
title_full_unstemmed |
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate |
title_sort |
hexakis(imidazole-n3)nickel(ii) oxydiacetate ethanol solvate |
publishDate |
1999 |
url |
http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec |
work_keys_str_mv |
AT perecm hexakisimidazolen3nickeliioxydiacetateethanolsolvate AT baggior hexakisimidazolen3nickeliioxydiacetateethanolsolvate AT garlandmt hexakisimidazolen3nickeliioxydiacetateethanolsolvate |
_version_ |
1769810111119753216 |