Effect of borate on the alkali-catalyzed isomerization of sugars
The addition of borate results in a greater conversion of aldose to ketose in alkali-catalyzed isomerizations. Borate appears to increase both the rate of formation and the maximum amount of ketose formed. The method of isomerization described may be adopted on a preparative scale, and would be espe...
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| Lenguaje: | English |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00027863_v82_n18_p4975_Mendicino |
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todo:paper_00027863_v82_n18_p4975_Mendicino2023-10-03T13:54:33Z Effect of borate on the alkali-catalyzed isomerization of sugars Mendicino, J.F. The addition of borate results in a greater conversion of aldose to ketose in alkali-catalyzed isomerizations. Borate appears to increase both the rate of formation and the maximum amount of ketose formed. The method of isomerization described may be adopted on a preparative scale, and would be especially useful when only small amounts of aldose are available or when identification of an aldose by isomerization to its ketose is desired. JOUR English info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00027863_v82_n18_p4975_Mendicino |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| language |
English |
| orig_language_str_mv |
English |
| description |
The addition of borate results in a greater conversion of aldose to ketose in alkali-catalyzed isomerizations. Borate appears to increase both the rate of formation and the maximum amount of ketose formed. The method of isomerization described may be adopted on a preparative scale, and would be especially useful when only small amounts of aldose are available or when identification of an aldose by isomerization to its ketose is desired. |
| format |
JOUR |
| author |
Mendicino, J.F. |
| spellingShingle |
Mendicino, J.F. Effect of borate on the alkali-catalyzed isomerization of sugars |
| author_facet |
Mendicino, J.F. |
| author_sort |
Mendicino, J.F. |
| title |
Effect of borate on the alkali-catalyzed isomerization of sugars |
| title_short |
Effect of borate on the alkali-catalyzed isomerization of sugars |
| title_full |
Effect of borate on the alkali-catalyzed isomerization of sugars |
| title_fullStr |
Effect of borate on the alkali-catalyzed isomerization of sugars |
| title_full_unstemmed |
Effect of borate on the alkali-catalyzed isomerization of sugars |
| title_sort |
effect of borate on the alkali-catalyzed isomerization of sugars |
| url |
http://hdl.handle.net/20.500.12110/paper_00027863_v82_n18_p4975_Mendicino |
| work_keys_str_mv |
AT mendicinojf effectofborateonthealkalicatalyzedisomerizationofsugars |
| _version_ |
1807319422443978752 |