Isotope Effects in Optical Rotation

A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approxim...

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Autores principales: Cohan, N.V., Hameka, H.F.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00027863_v88_n10_p2136_Cohan
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spelling todo:paper_00027863_v88_n10_p2136_Cohan2023-10-03T13:54:35Z Isotope Effects in Optical Rotation Cohan, N.V. Hameka, H.F. A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approximation for infrared light. Detailed calculations are performed for the molecules CHDBrCl, CCl35Cl37BrF, and CHDTBr. Various summation rules are derived for the vibrational rotatory strengths. © 1966, American Chemical Society. All rights reserved. Fil:Cohan, N.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approximation for infrared light. Detailed calculations are performed for the molecules CHDBrCl, CCl35Cl37BrF, and CHDTBr. Various summation rules are derived for the vibrational rotatory strengths. © 1966, American Chemical Society. All rights reserved.
format JOUR
author Cohan, N.V.
Hameka, H.F.
spellingShingle Cohan, N.V.
Hameka, H.F.
Isotope Effects in Optical Rotation
author_facet Cohan, N.V.
Hameka, H.F.
author_sort Cohan, N.V.
title Isotope Effects in Optical Rotation
title_short Isotope Effects in Optical Rotation
title_full Isotope Effects in Optical Rotation
title_fullStr Isotope Effects in Optical Rotation
title_full_unstemmed Isotope Effects in Optical Rotation
title_sort isotope effects in optical rotation
url http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
work_keys_str_mv AT cohannv isotopeeffectsinopticalrotation
AT hamekahf isotopeeffectsinopticalrotation
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