The mechanism of oxidation of 3-mercaptopropionic acid

The mechanism of the oxidation of 3-mercaptopropionic acid (3-MPA) by hydrogen peroxide was studied in the acidic pH range. The nucleophilic attack by sulphur on the peroxide bond controls the rate. Extrapolation of the pH dependency suggests that the rate of attack by the deprotonated dianion is hi...

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Detalles Bibliográficos
Autores principales:	Forlano, P., Olabe, J.A., Magallanes, J.F., Blesa, M.A.
Formato:	JOUR
Materias:	3-mercaptopropionic acid Autooxidation Electrochemistry Kinetics Catalysis Charge transfer Cyclic voltammetry Electrons Hydrogen peroxide Iron compounds Organic acids pH Polarographic analysis Reaction kinetics Deprotonated dianion Mercaptopropionic acid Nucleophilic attack Second electron transfer step Oxidation
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00084042_v75_n1_p9_Forlano
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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