On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes

Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is fo...

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Autores principales: Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00134686_v35_n2_p497_Caram
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00134686_v35_n2_p497_Caram2023-10-03T14:10:56Z On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes Caram, J.A. Martins, M.E. Gros, E.G. Marschoff, C.M. Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is formed by homogeneous reaction. Other minor products, including the new molecule 8-acetamido-2,4,8-trimethyl-4-bromomethyl-3-aza-bicyclo |3.3.1| non-2-ene (4), were identified. © 1990. Fil:Caram, J.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Marschoff, C.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00134686_v35_n2_p497_Caram
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is formed by homogeneous reaction. Other minor products, including the new molecule 8-acetamido-2,4,8-trimethyl-4-bromomethyl-3-aza-bicyclo |3.3.1| non-2-ene (4), were identified. © 1990.
format JOUR
author Caram, J.A.
Martins, M.E.
Gros, E.G.
Marschoff, C.M.
spellingShingle Caram, J.A.
Martins, M.E.
Gros, E.G.
Marschoff, C.M.
On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
author_facet Caram, J.A.
Martins, M.E.
Gros, E.G.
Marschoff, C.M.
author_sort Caram, J.A.
title On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
title_short On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
title_full On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
title_fullStr On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
title_full_unstemmed On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
title_sort on the anodic polarization of limonene in br- containing acetonitrile solutions on platinum electrodes
url http://hdl.handle.net/20.500.12110/paper_00134686_v35_n2_p497_Caram
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AT martinsme ontheanodicpolarizationoflimoneneinbrcontainingacetonitrilesolutionsonplatinumelectrodes
AT groseg ontheanodicpolarizationoflimoneneinbrcontainingacetonitrilesolutionsonplatinumelectrodes
AT marschoffcm ontheanodicpolarizationoflimoneneinbrcontainingacetonitrilesolutionsonplatinumelectrodes
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