On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes
Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is fo...
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| Autores principales: | , , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00134686_v35_n2_p497_Caram |
| Aporte de: |
| Sumario: | Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is formed by homogeneous reaction. Other minor products, including the new molecule 8-acetamido-2,4,8-trimethyl-4-bromomethyl-3-aza-bicyclo |3.3.1| non-2-ene (4), were identified. © 1990. |
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