Nitrosyl-centered redox and acid-base interconversions in [Ru(Me 3[9]aneN3)(bpy)(NO)]3,2,1+. The p K a of HNO for its nitroxyl derivative in aqueous solution
This work reports the preparation of a new 6-coordinated nitrosyl compound and its use as a model to explore the redox and acid-base properties of the three redox states of bound nitrosyl (formally NO+, NO •, NO-/HNO) in {RuNO}6,7,8 species. We prepared the octahedral {RuNO}6 complex [Ru(Me3[9] aneN...
Guardado en:
| Autores principales: | Codesido, N.O., Weyhermüller, T., Olabe, J.A., Slep, L.D. |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v53_n2_p981_Codesido |
| Aporte de: |
Ejemplares similares
-
Nitrosyl-centered redox and acid-base interconversions in [Ru(Me 3[9]aneN3)(bpy)(NO)]3,2,1+. The p K a of HNO for its nitroxyl derivative in aqueous solution
Publicado: (2014) -
Remarkable Changes of the Acidity of Bound Nitroxyl (HNO) in the [Ru(Me3[9]aneN3)(L2)(NO)]n+ Family (n = 1-3). Systematic Structural and Chemical Exploration and Bioinorganic Chemistry Implications
por: Levin, N., et al. -
Remarkable Changes of the Acidity of Bound Nitroxyl (HNO) in the [Ru(Me3[9]aneN3)(L2)(NO)]n+ Family (n = 1-3). Systematic Structural and Chemical Exploration and Bioinorganic Chemistry Implications
Publicado: (2018) -
Reactivity of iron(II)-bound nitrosyl hydride (HNO, nitroxyl) in aqueous solution
por: Montenegro, A.C., et al. -
Reactivity of iron(II)-bound nitrosyl hydride (HNO, nitroxyl) in aqueous solution
Publicado: (2013)