One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction

We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low...

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Autores principales: Lazzarini, I.C., Carrella, L., Rentschler, E., Alborés, P.
Formato: JOUR
Materias:
Magnetic properties
Manganese(III)
One dimensional chain
Schiff base
Symmetric H-bond
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00201693_v453_n_p692_Lazzarini
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spelling todo:paper_00201693_v453_n_p692_Lazzarini2023-10-03T14:17:23Z One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction Lazzarini, I.C. Carrella, L. Rentschler, E. Alborés, P. Magnetic properties Manganese(III) One dimensional chain Schiff base Symmetric H-bond We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway. © 2016 Elsevier B.V. Fil:Alborés, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Magnetic properties
Manganese(III)
One dimensional chain
Schiff base
Symmetric H-bond
spellingShingle Magnetic properties
Manganese(III)
One dimensional chain
Schiff base
Symmetric H-bond
Lazzarini, I.C.
Carrella, L.
Rentschler, E.
Alborés, P.
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
topic_facet Magnetic properties
Manganese(III)
One dimensional chain
Schiff base
Symmetric H-bond
description We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway. © 2016 Elsevier B.V.
format JOUR
author Lazzarini, I.C.
Carrella, L.
Rentschler, E.
Alborés, P.
author_facet Lazzarini, I.C.
Carrella, L.
Rentschler, E.
Alborés, P.
author_sort Lazzarini, I.C.
title One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_short One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_full One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_fullStr One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_full_unstemmed One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_sort one dimensional mn(iii) schiff-base complex organization through very strong symmetrical h-bond interaction
url http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini
work_keys_str_mv AT lazzariniic onedimensionalmniiischiffbasecomplexorganizationthroughverystrongsymmetricalhbondinteraction
AT carrellal onedimensionalmniiischiffbasecomplexorganizationthroughverystrongsymmetricalhbondinteraction
AT rentschlere onedimensionalmniiischiffbasecomplexorganizationthroughverystrongsymmetricalhbondinteraction
AT alboresp onedimensionalmniiischiffbasecomplexorganizationthroughverystrongsymmetricalhbondinteraction
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