One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction

We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low...

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Detalles Bibliográficos
Autores principales: Lazzarini, I.C., Carrella, L., Rentschler, E., Alborés, P.
Formato: JOUR
Materias:
Magnetic properties
Manganese(III)
One dimensional chain
Schiff base
Symmetric H-bond
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201693_v453_n_p692_Lazzarini
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway. © 2016 Elsevier B.V.

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