Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine
The reaction between borine carbonyl and trimethylamine has been studied from 207·3 to 273·2°K. Below 273·2°K the reaction is second-order: d(CO)/dt = k(BH3CO)(Me3N). The Arrhenius parameters associated with this SN2 reaction are E = 8·60 ± 0·30 kcal./mole, and A = 10 9·82 ± 0·27 c.c./mole sec. At 2...
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todo:paper_00224944_v_n_p1034_Grotewold2023-10-03T14:33:20Z Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine Grotewold, J. Lissi, E.A. Villa, A.E. The reaction between borine carbonyl and trimethylamine has been studied from 207·3 to 273·2°K. Below 273·2°K the reaction is second-order: d(CO)/dt = k(BH3CO)(Me3N). The Arrhenius parameters associated with this SN2 reaction are E = 8·60 ± 0·30 kcal./mole, and A = 10 9·82 ± 0·27 c.c./mole sec. At 273·2°K the unimolecular rupture of the B-C bond becomes important as a rate-controlling step. Fil:Villa, A.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00224944_v_n_p1034_Grotewold |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The reaction between borine carbonyl and trimethylamine has been studied from 207·3 to 273·2°K. Below 273·2°K the reaction is second-order: d(CO)/dt = k(BH3CO)(Me3N). The Arrhenius parameters associated with this SN2 reaction are E = 8·60 ± 0·30 kcal./mole, and A = 10 9·82 ± 0·27 c.c./mole sec. At 273·2°K the unimolecular rupture of the B-C bond becomes important as a rate-controlling step. |
| format |
JOUR |
| author |
Grotewold, J. Lissi, E.A. Villa, A.E. |
| spellingShingle |
Grotewold, J. Lissi, E.A. Villa, A.E. Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| author_facet |
Grotewold, J. Lissi, E.A. Villa, A.E. |
| author_sort |
Grotewold, J. |
| title |
Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| title_short |
Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| title_full |
Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| title_fullStr |
Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| title_full_unstemmed |
Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| title_sort |
reactions of co-ordinated boron compounds in the gas phase. part i. borine carbonyl and trimethylamine |
| url |
http://hdl.handle.net/20.500.12110/paper_00224944_v_n_p1034_Grotewold |
| work_keys_str_mv |
AT grotewoldj reactionsofcoordinatedboroncompoundsinthegasphasepartiborinecarbonylandtrimethylamine AT lissiea reactionsofcoordinatedboroncompoundsinthegasphasepartiborinecarbonylandtrimethylamine AT villaae reactionsofcoordinatedboroncompoundsinthegasphasepartiborinecarbonylandtrimethylamine |
| _version_ |
1807317549478576128 |