Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine
The reaction between borine carbonyl and trimethylamine has been studied from 207·3 to 273·2°K. Below 273·2°K the reaction is second-order: d(CO)/dt = k(BH3CO)(Me3N). The Arrhenius parameters associated with this SN2 reaction are E = 8·60 ± 0·30 kcal./mole, and A = 10 9·82 ± 0·27 c.c./mole sec. At 2...
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| Autores principales: | Grotewold, J., Lissi, E.A., Villa, A.E. |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00224944_v_n_p1034_Grotewold |
| Aporte de: |
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