Biosynthesis of skimmianine in Fagara coco
Fagara coco plants were inoculated in separate experiments with sodium acetate 1-14C, sodium formate-14C, mevalonic acid-4-14C, mevalonic acid-5-14C, 3,3-dimethylallyl alcohol-1-14C, and 3,3-dimethylacrylic acid-1-14C. The furanoquinoline alkaloid skimmianine was isolated from each plant and degrade...
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todo:paper_00319422_v10_n7_p1515_Colonna2023-10-03T14:43:48Z Biosynthesis of skimmianine in Fagara coco Colonna, A.O. Gros, E.G. Fagara coco plants were inoculated in separate experiments with sodium acetate 1-14C, sodium formate-14C, mevalonic acid-4-14C, mevalonic acid-5-14C, 3,3-dimethylallyl alcohol-1-14C, and 3,3-dimethylacrylic acid-1-14C. The furanoquinoline alkaloid skimmianine was isolated from each plant and degraded to determine the activity at C-2 and C-3. The result from the acetate experiment confirmed previous findings for labelling only in the quinoline moiety; the same result was encountered with labelled dimethylacrylic acid. Sodium formate labelled mainly the methoxy groups, while the results from both mevalonic acids and dimethylallyl alcohol clearly indicated that C-2 and C-3 of the furan ring are derived from C-4 and C-5 of mevalonic acid respectively. © 1971. Fil:Colonna, A.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00319422_v10_n7_p1515_Colonna |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
Fagara coco plants were inoculated in separate experiments with sodium acetate 1-14C, sodium formate-14C, mevalonic acid-4-14C, mevalonic acid-5-14C, 3,3-dimethylallyl alcohol-1-14C, and 3,3-dimethylacrylic acid-1-14C. The furanoquinoline alkaloid skimmianine was isolated from each plant and degraded to determine the activity at C-2 and C-3. The result from the acetate experiment confirmed previous findings for labelling only in the quinoline moiety; the same result was encountered with labelled dimethylacrylic acid. Sodium formate labelled mainly the methoxy groups, while the results from both mevalonic acids and dimethylallyl alcohol clearly indicated that C-2 and C-3 of the furan ring are derived from C-4 and C-5 of mevalonic acid respectively. © 1971. |
| format |
JOUR |
| author |
Colonna, A.O. Gros, E.G. |
| spellingShingle |
Colonna, A.O. Gros, E.G. Biosynthesis of skimmianine in Fagara coco |
| author_facet |
Colonna, A.O. Gros, E.G. |
| author_sort |
Colonna, A.O. |
| title |
Biosynthesis of skimmianine in Fagara coco |
| title_short |
Biosynthesis of skimmianine in Fagara coco |
| title_full |
Biosynthesis of skimmianine in Fagara coco |
| title_fullStr |
Biosynthesis of skimmianine in Fagara coco |
| title_full_unstemmed |
Biosynthesis of skimmianine in Fagara coco |
| title_sort |
biosynthesis of skimmianine in fagara coco |
| url |
http://hdl.handle.net/20.500.12110/paper_00319422_v10_n7_p1515_Colonna |
| work_keys_str_mv |
AT colonnaao biosynthesisofskimmianineinfagaracoco AT groseg biosynthesisofskimmianineinfagaracoco |
| _version_ |
1807318738164252672 |