Sulphated xylogalactans from Nothogenia fastigiata
Fractionation of the Cetrimide salt of the sulphated polysaccharides of Nothogenia fastigiata led to the isolation of a complex product constituted by a xylogalactan sulphate and a xylomannan sulphate. Its structural study by methylation and desulphation-methylation analyses and 13C NMR spectroscopy...
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todo:paper_00319422_v36_n1_p97_Matulewicz2023-10-03T14:44:16Z Sulphated xylogalactans from Nothogenia fastigiata Matulewicz, M.C. Haines, H.H. Cerezo, A.A. Nothogenia fastigiata seaweed structural analysis. sulphated xylogalactans Fractionation of the Cetrimide salt of the sulphated polysaccharides of Nothogenia fastigiata led to the isolation of a complex product constituted by a xylogalactan sulphate and a xylomannan sulphate. Its structural study by methylation and desulphation-methylation analyses and 13C NMR spectroscopy indicated for the xylogalactan sulphate a backbone formed by 4-linked α-l-galactopyranose and 3-linked β-d-galactopyranose. The α-l-galactopyranosyl units are either 6-sulphated having single stubs of (1 → 3)-linked xylose or galactose, 3-sulphated or non-substituted. The β-d-galactopyranosyl residues are non-substituted or 4-sulphated. The xylomannan sulphate is similar to that previously isolated from this seaweed. © 1994. Fil:Matulewicz, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00319422_v36_n1_p97_Matulewicz |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Nothogenia fastigiata seaweed structural analysis. sulphated xylogalactans |
| spellingShingle |
Nothogenia fastigiata seaweed structural analysis. sulphated xylogalactans Matulewicz, M.C. Haines, H.H. Cerezo, A.A. Sulphated xylogalactans from Nothogenia fastigiata |
| topic_facet |
Nothogenia fastigiata seaweed structural analysis. sulphated xylogalactans |
| description |
Fractionation of the Cetrimide salt of the sulphated polysaccharides of Nothogenia fastigiata led to the isolation of a complex product constituted by a xylogalactan sulphate and a xylomannan sulphate. Its structural study by methylation and desulphation-methylation analyses and 13C NMR spectroscopy indicated for the xylogalactan sulphate a backbone formed by 4-linked α-l-galactopyranose and 3-linked β-d-galactopyranose. The α-l-galactopyranosyl units are either 6-sulphated having single stubs of (1 → 3)-linked xylose or galactose, 3-sulphated or non-substituted. The β-d-galactopyranosyl residues are non-substituted or 4-sulphated. The xylomannan sulphate is similar to that previously isolated from this seaweed. © 1994. |
| format |
JOUR |
| author |
Matulewicz, M.C. Haines, H.H. Cerezo, A.A. |
| author_facet |
Matulewicz, M.C. Haines, H.H. Cerezo, A.A. |
| author_sort |
Matulewicz, M.C. |
| title |
Sulphated xylogalactans from Nothogenia fastigiata |
| title_short |
Sulphated xylogalactans from Nothogenia fastigiata |
| title_full |
Sulphated xylogalactans from Nothogenia fastigiata |
| title_fullStr |
Sulphated xylogalactans from Nothogenia fastigiata |
| title_full_unstemmed |
Sulphated xylogalactans from Nothogenia fastigiata |
| title_sort |
sulphated xylogalactans from nothogenia fastigiata |
| url |
http://hdl.handle.net/20.500.12110/paper_00319422_v36_n1_p97_Matulewicz |
| work_keys_str_mv |
AT matulewiczmc sulphatedxylogalactansfromnothogeniafastigiata AT haineshh sulphatedxylogalactansfromnothogeniafastigiata AT cerezoaa sulphatedxylogalactansfromnothogeniafastigiata |
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1807319782054166528 |