Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature
The formic acid-mediated photoreduction of aromatic nitro compounds in room temperature acetonitrile solutions was investigated. This mild photoreduction can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min to 1 h), and allows a very clean method f...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00404039_v49_n9_p1555_Cors |
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todo:paper_00404039_v49_n9_p1555_Cors2023-10-03T14:50:55Z Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature Cors, A. Bonesi, S.M. Erra-Balsells, R. acetonitrile formic acid functional group nitro derivative polycyclic aromatic hydrocarbon derivative article biotransformation photochemistry quantum yield reaction analysis reaction time reduction room temperature The formic acid-mediated photoreduction of aromatic nitro compounds in room temperature acetonitrile solutions was investigated. This mild photoreduction can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min to 1 h), and allows a very clean method for the conversion of nitro arenes to amines. Also, the photoreduction, as a convenient, versatile and general method, applies efficiently to polycyclic and heterocyclic nitro arenes. © 2007 Elsevier Ltd. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00404039_v49_n9_p1555_Cors |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
acetonitrile formic acid functional group nitro derivative polycyclic aromatic hydrocarbon derivative article biotransformation photochemistry quantum yield reaction analysis reaction time reduction room temperature |
| spellingShingle |
acetonitrile formic acid functional group nitro derivative polycyclic aromatic hydrocarbon derivative article biotransformation photochemistry quantum yield reaction analysis reaction time reduction room temperature Cors, A. Bonesi, S.M. Erra-Balsells, R. Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| topic_facet |
acetonitrile formic acid functional group nitro derivative polycyclic aromatic hydrocarbon derivative article biotransformation photochemistry quantum yield reaction analysis reaction time reduction room temperature |
| description |
The formic acid-mediated photoreduction of aromatic nitro compounds in room temperature acetonitrile solutions was investigated. This mild photoreduction can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min to 1 h), and allows a very clean method for the conversion of nitro arenes to amines. Also, the photoreduction, as a convenient, versatile and general method, applies efficiently to polycyclic and heterocyclic nitro arenes. © 2007 Elsevier Ltd. All rights reserved. |
| format |
JOUR |
| author |
Cors, A. Bonesi, S.M. Erra-Balsells, R. |
| author_facet |
Cors, A. Bonesi, S.M. Erra-Balsells, R. |
| author_sort |
Cors, A. |
| title |
Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| title_short |
Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| title_full |
Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| title_fullStr |
Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| title_full_unstemmed |
Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| title_sort |
photoreduction of nitro arenes by formic acid in acetonitrile at room temperature |
| url |
http://hdl.handle.net/20.500.12110/paper_00404039_v49_n9_p1555_Cors |
| work_keys_str_mv |
AT corsa photoreductionofnitroarenesbyformicacidinacetonitrileatroomtemperature AT bonesism photoreductionofnitroarenesbyformicacidinacetonitrileatroomtemperature AT errabalsellsr photoreductionofnitroarenesbyformicacidinacetonitrileatroomtemperature |
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1807322277616812032 |