Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isop...
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todo:paper_00456470_v_n_p414_Braslavsky2023-10-03T14:51:56Z Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide Braslavsky, S.E. Grotewold, J. Lissi, E.A. The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals. Fil:Braslavsky, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals. |
| format |
JOUR |
| author |
Braslavsky, S.E. Grotewold, J. Lissi, E.A. |
| spellingShingle |
Braslavsky, S.E. Grotewold, J. Lissi, E.A. Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| author_facet |
Braslavsky, S.E. Grotewold, J. Lissi, E.A. |
| author_sort |
Braslavsky, S.E. |
| title |
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| title_short |
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| title_full |
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| title_fullStr |
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| title_full_unstemmed |
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| title_sort |
alkyl iodides as a source of alkyl radicals. part i. mechanism of the gas-phase photolysis of isopropyl iodide |
| url |
http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky |
| work_keys_str_mv |
AT braslavskyse alkyliodidesasasourceofalkylradicalspartimechanismofthegasphasephotolysisofisopropyliodide AT grotewoldj alkyliodidesasasourceofalkylradicalspartimechanismofthegasphasephotolysisofisopropyliodide AT lissiea alkyliodidesasasourceofalkylradicalspartimechanismofthegasphasephotolysisofisopropyliodide |
| _version_ |
1807322579583631360 |