Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide

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The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isop...

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Autores principales: Braslavsky, S.E., Grotewold, J., Lissi, E.A.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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