Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.

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The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex for...

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Autores principales: Rebollo Paz, M.B., Buep, A.H., Baron, M.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_01677322_v38_n3-4_p225_RebolloPaz
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spelling todo:paper_01677322_v38_n3-4_p225_RebolloPaz2023-10-03T15:05:18Z Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. Rebollo Paz, M.B. Buep, A.H. Baron, M. The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex formation is introduced. As a result the range of validity of the model extends into the non-dilute region and up to the limit where complexes other than 1:1 appear. These changes allow also to calculate the equilibrium constant (K) for the 1:1 complex from dielectric measurements in the dilute region. The values are in good agreement with those found in the literature. © 1988. Fil:Rebollo Paz, M.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Buep, A.H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baron, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex formation is introduced. As a result the range of validity of the model extends into the non-dilute region and up to the limit where complexes other than 1:1 appear. These changes allow also to calculate the equilibrium constant (K) for the 1:1 complex from dielectric measurements in the dilute region. The values are in good agreement with those found in the literature. © 1988.
format JOUR
author Rebollo Paz, M.B.
Buep, A.H.
Baron, M.
spellingShingle Rebollo Paz, M.B.
Buep, A.H.
Baron, M.
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
author_facet Rebollo Paz, M.B.
Buep, A.H.
Baron, M.
author_sort Rebollo Paz, M.B.
title Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
title_short Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
title_full Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
title_fullStr Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
title_full_unstemmed Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
title_sort dielectric properties of binary systems 8. improved model for alcohol/non polar systems.
url http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz
work_keys_str_mv AT rebollopazmb dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems
AT buepah dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems
AT baronm dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems
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