Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide

The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give...

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Detalles Bibliográficos
Autores principales: Trápani, C., Escola, N., Doctorovich, F.
Formato: JOUR
Materias:
Nucleophilic attacks
Concentration (process)
Fourier transform infrared spectroscopy
Lithium compounds
Mixtures
Nuclear magnetic resonance spectroscopy
Phase equilibria
Stoichiometry
Ultraviolet spectroscopy
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02767333_v21_n10_p2021_Trapani
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_02767333_v21_n10_p2021_Trapani2023-10-03T15:15:59Z Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide Trápani, C. Escola, N. Doctorovich, F. Nucleophilic attacks Concentration (process) Fourier transform infrared spectroscopy Lithium compounds Mixtures Nuclear magnetic resonance spectroscopy Phase equilibria Stoichiometry Ultraviolet spectroscopy Organometallics The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give a strong indication that diazoates (and/or diazoic acids) are intermediates in the reactions of amines with these nitrosyl complexes. Fil:Escola, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02767333_v21_n10_p2021_Trapani
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Nucleophilic attacks
Concentration (process)
Fourier transform infrared spectroscopy
Lithium compounds
Mixtures
Nuclear magnetic resonance spectroscopy
Phase equilibria
Stoichiometry
Ultraviolet spectroscopy
Organometallics
spellingShingle Nucleophilic attacks
Concentration (process)
Fourier transform infrared spectroscopy
Lithium compounds
Mixtures
Nuclear magnetic resonance spectroscopy
Phase equilibria
Stoichiometry
Ultraviolet spectroscopy
Organometallics
Trápani, C.
Escola, N.
Doctorovich, F.
Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
topic_facet Nucleophilic attacks
Concentration (process)
Fourier transform infrared spectroscopy
Lithium compounds
Mixtures
Nuclear magnetic resonance spectroscopy
Phase equilibria
Stoichiometry
Ultraviolet spectroscopy
Organometallics
description The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give a strong indication that diazoates (and/or diazoic acids) are intermediates in the reactions of amines with these nitrosyl complexes.
format JOUR
author Trápani, C.
Escola, N.
Doctorovich, F.
author_facet Trápani, C.
Escola, N.
Doctorovich, F.
author_sort Trápani, C.
title Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
title_short Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
title_full Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
title_fullStr Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
title_full_unstemmed Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
title_sort formation of n-butyldiazoate by reaction of [m(cn)5no]2- (m = fe, ru, os) with lithium n-butylamide
url http://hdl.handle.net/20.500.12110/paper_02767333_v21_n10_p2021_Trapani
work_keys_str_mv AT trapanic formationofnbutyldiazoatebyreactionofmcn5no2mferuoswithlithiumnbutylamide
AT escolan formationofnbutyldiazoatebyreactionofmcn5no2mferuoswithlithiumnbutylamide
AT doctorovichf formationofnbutyldiazoatebyreactionofmcn5no2mferuoswithlithiumnbutylamide
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