Synthesis of [20,21‐13C2]‐progesterone
The synthesis of, [20,21‐13C2]‐progesterone (9) from androst‐4‐ene‐3,17‐dione (1) is described. Labels were introduced by two procedures, namely, condensation of 1 with K13CN and Grignard reaction of nitrile derivative 7 with [13C]‐methylmagnesium iodide. Location of labels was confirmed by 13C‐NMR...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03624803_v29_n7_p805_Caballero |
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todo:paper_03624803_v29_n7_p805_Caballero2023-10-03T15:27:06Z Synthesis of [20,21‐13C2]‐progesterone Caballero, G.M. Gros, E.G. synthesis [20,21‐13C2]‐progesterone carbon 13 progesterone article controlled study hormone synthesis isotope labeling The synthesis of, [20,21‐13C2]‐progesterone (9) from androst‐4‐ene‐3,17‐dione (1) is described. Labels were introduced by two procedures, namely, condensation of 1 with K13CN and Grignard reaction of nitrile derivative 7 with [13C]‐methylmagnesium iodide. Location of labels was confirmed by 13C‐NMR spectroscopy. Copyright © 1991 John Wiley & Sons, Ltd. Fil:Caballero, G.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03624803_v29_n7_p805_Caballero |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
synthesis [20,21‐13C2]‐progesterone carbon 13 progesterone article controlled study hormone synthesis isotope labeling |
| spellingShingle |
synthesis [20,21‐13C2]‐progesterone carbon 13 progesterone article controlled study hormone synthesis isotope labeling Caballero, G.M. Gros, E.G. Synthesis of [20,21‐13C2]‐progesterone |
| topic_facet |
synthesis [20,21‐13C2]‐progesterone carbon 13 progesterone article controlled study hormone synthesis isotope labeling |
| description |
The synthesis of, [20,21‐13C2]‐progesterone (9) from androst‐4‐ene‐3,17‐dione (1) is described. Labels were introduced by two procedures, namely, condensation of 1 with K13CN and Grignard reaction of nitrile derivative 7 with [13C]‐methylmagnesium iodide. Location of labels was confirmed by 13C‐NMR spectroscopy. Copyright © 1991 John Wiley & Sons, Ltd. |
| format |
JOUR |
| author |
Caballero, G.M. Gros, E.G. |
| author_facet |
Caballero, G.M. Gros, E.G. |
| author_sort |
Caballero, G.M. |
| title |
Synthesis of [20,21‐13C2]‐progesterone |
| title_short |
Synthesis of [20,21‐13C2]‐progesterone |
| title_full |
Synthesis of [20,21‐13C2]‐progesterone |
| title_fullStr |
Synthesis of [20,21‐13C2]‐progesterone |
| title_full_unstemmed |
Synthesis of [20,21‐13C2]‐progesterone |
| title_sort |
synthesis of [20,21‐13c2]‐progesterone |
| url |
http://hdl.handle.net/20.500.12110/paper_03624803_v29_n7_p805_Caballero |
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AT caballerogm synthesisof202113c2progesterone AT groseg synthesisof202113c2progesterone |
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1807315273961701376 |