Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose

The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a s...

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Autores principales:	Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I.
Formato:	JOUR
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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spelling	todo:paper_07328303_v14_n4-5_p525_Moradei2023-10-03T15:37:30Z Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose Moradei, O. Mortier, C.D. Alicia, F.A. Joachim, J. Ihiem, I. The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved. Fil:Moradei, O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description	The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved.
format	JOUR
author	Moradei, O. Mortier, C.D. Alicia, F.A. Joachim, J. Ihiem, I.
spellingShingle	Moradei, O. Mortier, C.D. Alicia, F.A. Joachim, J. Ihiem, I. Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
author_facet	Moradei, O. Mortier, C.D. Alicia, F.A. Joachim, J. Ihiem, I.
author_sort	Moradei, O.
title	Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_short	Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_full	Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_fullStr	Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_full_unstemmed	Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_sort	simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane b2 (txb2) precursors, from d-galactose
url	http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
work_keys_str_mv	AT moradeio simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose AT mortiercd simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose AT aliciafa simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose AT joachimj simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose AT ihiemi simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose
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Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose

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