13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers

The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley &a...

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Autores principales: Doller, D., Gros, E.G.
Formato: JOUR
Materias:
13C NMR spectra
3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one
3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one
Acid‐catalysed rearrangement
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_07491581_v26_n7_p539_Doller2023-10-03T15:39:17Z 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers Doller, D. Gros, E.G. 13C NMR spectra 3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one 3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one Acid‐catalysed rearrangement The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley & Sons, Ltd. Fil:Doller, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 13C NMR spectra
3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one
3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one
Acid‐catalysed rearrangement
spellingShingle 13C NMR spectra
3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one
3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one
Acid‐catalysed rearrangement
Doller, D.
Gros, E.G.
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
topic_facet 13C NMR spectra
3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one
3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one
Acid‐catalysed rearrangement
description The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley & Sons, Ltd.
format JOUR
author Doller, D.
Gros, E.G.
author_facet Doller, D.
Gros, E.G.
author_sort Doller, D.
title 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
title_short 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
title_full 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
title_fullStr 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
title_full_unstemmed 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
title_sort 13c nmr spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
url http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller
work_keys_str_mv AT dollerd 13cnmrspectroscopicstudyoftherearrangementof16bhydroxy17oxosteroidsto17bhydroxy16oxoisomers
AT groseg 13cnmrspectroscopicstudyoftherearrangementof16bhydroxy17oxosteroidsto17bhydroxy16oxoisomers
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