13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley &a...
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| Autores principales: | , |
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller |
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| Sumario: | The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley & Sons, Ltd. |
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