13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers

The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley &a...

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Detalles Bibliográficos
Autores principales: Doller, D., Gros, E.G.
Formato: JOUR
Materias:
13C NMR spectra
3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one
3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one
Acid‐catalysed rearrangement
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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