Carbonylation of cyclic lithium amides in the presence of transition metal salts
The effect of several transition metal halides on the rates and product distribution of the carbonylation of lithium-3-oxatetramethylenamide and lithium-pentamethylenamide in THF at 0°C was examined: It was found that whereas Ni(II) has almost no effect, Cu(I), Co(II) and Cr(III) produce a noticeabl...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_07921241_v18_n3_p147_Nudelman |
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todo:paper_07921241_v18_n3_p147_Nudelman2023-10-03T15:39:52Z Carbonylation of cyclic lithium amides in the presence of transition metal salts Nudelman, N.S. Linares, G.G. Schulz, H. The effect of several transition metal halides on the rates and product distribution of the carbonylation of lithium-3-oxatetramethylenamide and lithium-pentamethylenamide in THF at 0°C was examined: It was found that whereas Ni(II) has almost no effect, Cu(I), Co(II) and Cr(III) produce a noticeable inhibition, presumably due to the formation of hetero transition metal-lithium complexes. © 1995, Walter de Gruyter. All rights reserved. Fil:Schulz, H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_07921241_v18_n3_p147_Nudelman |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The effect of several transition metal halides on the rates and product distribution of the carbonylation of lithium-3-oxatetramethylenamide and lithium-pentamethylenamide in THF at 0°C was examined: It was found that whereas Ni(II) has almost no effect, Cu(I), Co(II) and Cr(III) produce a noticeable inhibition, presumably due to the formation of hetero transition metal-lithium complexes. © 1995, Walter de Gruyter. All rights reserved. |
| format |
JOUR |
| author |
Nudelman, N.S. Linares, G.G. Schulz, H. |
| spellingShingle |
Nudelman, N.S. Linares, G.G. Schulz, H. Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| author_facet |
Nudelman, N.S. Linares, G.G. Schulz, H. |
| author_sort |
Nudelman, N.S. |
| title |
Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| title_short |
Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| title_full |
Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| title_fullStr |
Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| title_full_unstemmed |
Carbonylation of cyclic lithium amides in the presence of transition metal salts |
| title_sort |
carbonylation of cyclic lithium amides in the presence of transition metal salts |
| url |
http://hdl.handle.net/20.500.12110/paper_07921241_v18_n3_p147_Nudelman |
| work_keys_str_mv |
AT nudelmanns carbonylationofcycliclithiumamidesinthepresenceoftransitionmetalsalts AT linaresgg carbonylationofcycliclithiumamidesinthepresenceoftransitionmetalsalts AT schulzh carbonylationofcycliclithiumamidesinthepresenceoftransitionmetalsalts |
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1807322230666821632 |