How the by-products hint at mechanisms and suggest new synthetic routes in some organolithium reactions

The recent proliferation of structural studies of organolithium reagents has led to an extended knowledge of the aggregation state of these pervasive synthetic intermediates. Nevertheless, detailed investigations of organolithium reaction mechanisms are still very limited. The most popular technique...

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Detalles Bibliográficos
Autores principales:	Nudelman, N.S., García, G.V., Velurtas, S.
Formato:	JOUR
Materias:	Anionic cyclization Ate complex Halogen-lithium exchange Li/oxygen carbenoid Lithium surface reactions Organolithium Agglomeration Decay (organic) Lithium Nuclear magnetic resonance Paramagnetic resonance Stereochemistry Ultraviolet spectroscopy Synthetic intermediates Chemical reactions
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_08943230_v15_n12_p903_Nudelman
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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