Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor
Five different cellulose-based fabrics were used to prepare activated carbon cloths (ACCs) by phosphoric acid activation at pre-established experimental conditions, in an attempt to explore the effect of the precursor's nature on properties of the resulting ACCs. Characterization by elemental a...
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todo:paper_09277757_v324_n1-3_p86_Ramos2023-10-03T15:47:07Z Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor Ramos, M.E. Bonelli, P.R. Cukierman, A.L. Activated carbon cloths Chemical activation Properties Adsorption Carbon Carbon nanotubes Charcoal Chemical activation Chemical modification Chemical properties Electric heating Electric properties Electron microscopes Electron microscopy Electron optics Fabrics Gas adsorption Gravimetric analysis Imaging techniques Microscopic examination Nitrogen Phosphoric acid Photoacoustic effect Scanning Scanning electron microscopy Thermogravimetric analysis (PL) properties acid activation Activated-carbon cloths BET surface areas Direct electrical heating Electrical (electronic) properties Elemental analysis (EA) Experimental conditions Physico chemicals Activated carbon activated carbon nitrogen adsorption article chemical composition electric resistance electricity heating physical chemistry porosity priority journal scanning electron microscopy textile thermogravimetry Five different cellulose-based fabrics were used to prepare activated carbon cloths (ACCs) by phosphoric acid activation at pre-established experimental conditions, in an attempt to explore the effect of the precursor's nature on properties of the resulting ACCs. Characterization by elemental analysis, nitrogen (77 K) adsorption, and scanning electron microscopy was carried out. Electrical properties of the developed ACCs were investigated to examine the possibility of regenerating the ACCs by direct electrical heating. Thermal behavior of the raw precursor and of one of the acid-treated fabrics was also studied by thermogravimetric analysis and noticeable differences due to the precursors' characteristics and acid impregnation were detected, respectively. The ACCs derived from a denim precursor showed BET surface area (784 m2 g-1) and total pore volume (0.40 cm3 g-1) lower than those obtained from the four other precursors (1058-1183 m2 g-1, 0.55-0.67 cm3 g-1), whereas carbon content and yield for the former were higher. Morphology and physical appearance of the ACCs were dependent on the raw fabric employed, with most of the samples presenting well-preserved fibres integrity. Besides, the denim-derived ACCs also showed the lowest electrical resistivity (∼8.10-3 Ωm). It was properly correlated with the elemental carbon content and total pore volume of the developed ACCs. © 2008 Elsevier B.V. All rights reserved. Fil:Ramos, M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bonelli, P.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09277757_v324_n1-3_p86_Ramos |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Activated carbon cloths Chemical activation Properties Adsorption Carbon Carbon nanotubes Charcoal Chemical activation Chemical modification Chemical properties Electric heating Electric properties Electron microscopes Electron microscopy Electron optics Fabrics Gas adsorption Gravimetric analysis Imaging techniques Microscopic examination Nitrogen Phosphoric acid Photoacoustic effect Scanning Scanning electron microscopy Thermogravimetric analysis (PL) properties acid activation Activated-carbon cloths BET surface areas Direct electrical heating Electrical (electronic) properties Elemental analysis (EA) Experimental conditions Physico chemicals Activated carbon activated carbon nitrogen adsorption article chemical composition electric resistance electricity heating physical chemistry porosity priority journal scanning electron microscopy textile thermogravimetry |
spellingShingle |
Activated carbon cloths Chemical activation Properties Adsorption Carbon Carbon nanotubes Charcoal Chemical activation Chemical modification Chemical properties Electric heating Electric properties Electron microscopes Electron microscopy Electron optics Fabrics Gas adsorption Gravimetric analysis Imaging techniques Microscopic examination Nitrogen Phosphoric acid Photoacoustic effect Scanning Scanning electron microscopy Thermogravimetric analysis (PL) properties acid activation Activated-carbon cloths BET surface areas Direct electrical heating Electrical (electronic) properties Elemental analysis (EA) Experimental conditions Physico chemicals Activated carbon activated carbon nitrogen adsorption article chemical composition electric resistance electricity heating physical chemistry porosity priority journal scanning electron microscopy textile thermogravimetry Ramos, M.E. Bonelli, P.R. Cukierman, A.L. Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
topic_facet |
Activated carbon cloths Chemical activation Properties Adsorption Carbon Carbon nanotubes Charcoal Chemical activation Chemical modification Chemical properties Electric heating Electric properties Electron microscopes Electron microscopy Electron optics Fabrics Gas adsorption Gravimetric analysis Imaging techniques Microscopic examination Nitrogen Phosphoric acid Photoacoustic effect Scanning Scanning electron microscopy Thermogravimetric analysis (PL) properties acid activation Activated-carbon cloths BET surface areas Direct electrical heating Electrical (electronic) properties Elemental analysis (EA) Experimental conditions Physico chemicals Activated carbon activated carbon nitrogen adsorption article chemical composition electric resistance electricity heating physical chemistry porosity priority journal scanning electron microscopy textile thermogravimetry |
description |
Five different cellulose-based fabrics were used to prepare activated carbon cloths (ACCs) by phosphoric acid activation at pre-established experimental conditions, in an attempt to explore the effect of the precursor's nature on properties of the resulting ACCs. Characterization by elemental analysis, nitrogen (77 K) adsorption, and scanning electron microscopy was carried out. Electrical properties of the developed ACCs were investigated to examine the possibility of regenerating the ACCs by direct electrical heating. Thermal behavior of the raw precursor and of one of the acid-treated fabrics was also studied by thermogravimetric analysis and noticeable differences due to the precursors' characteristics and acid impregnation were detected, respectively. The ACCs derived from a denim precursor showed BET surface area (784 m2 g-1) and total pore volume (0.40 cm3 g-1) lower than those obtained from the four other precursors (1058-1183 m2 g-1, 0.55-0.67 cm3 g-1), whereas carbon content and yield for the former were higher. Morphology and physical appearance of the ACCs were dependent on the raw fabric employed, with most of the samples presenting well-preserved fibres integrity. Besides, the denim-derived ACCs also showed the lowest electrical resistivity (∼8.10-3 Ωm). It was properly correlated with the elemental carbon content and total pore volume of the developed ACCs. © 2008 Elsevier B.V. All rights reserved. |
format |
JOUR |
author |
Ramos, M.E. Bonelli, P.R. Cukierman, A.L. |
author_facet |
Ramos, M.E. Bonelli, P.R. Cukierman, A.L. |
author_sort |
Ramos, M.E. |
title |
Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
title_short |
Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
title_full |
Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
title_fullStr |
Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
title_full_unstemmed |
Physico-chemical and electrical properties of activated carbon cloths. Effect of inherent nature of the fabric precursor |
title_sort |
physico-chemical and electrical properties of activated carbon cloths. effect of inherent nature of the fabric precursor |
url |
http://hdl.handle.net/20.500.12110/paper_09277757_v324_n1-3_p86_Ramos |
work_keys_str_mv |
AT ramosme physicochemicalandelectricalpropertiesofactivatedcarbonclothseffectofinherentnatureofthefabricprecursor AT bonellipr physicochemicalandelectricalpropertiesofactivatedcarbonclothseffectofinherentnatureofthefabricprecursor AT cukiermanal physicochemicalandelectricalpropertiesofactivatedcarbonclothseffectofinherentnatureofthefabricprecursor |
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1807323001964724224 |