Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics
The photochemical behaviour of full-aromatic β-carbolines (nor-harmane, harmane and harmine) in chloroform medium and the corresponding UV absorption and fluorescence emission spectra are discussed. Irreversible electron transfer from the singlet excited β-carboline molecule to the chloroform molecu...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_10106030_v77_n2-3_p149_Biondic |
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todo:paper_10106030_v77_n2-3_p149_Biondic2023-10-03T15:56:04Z Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics Biondic, M.C. Erra-Balsells, R. The photochemical behaviour of full-aromatic β-carbolines (nor-harmane, harmane and harmine) in chloroform medium and the corresponding UV absorption and fluorescence emission spectra are discussed. Irreversible electron transfer from the singlet excited β-carboline molecule to the chloroform molecule in the transient excited charge transfer complex has been proposed as the primary photochemical process initiating the mechanism of secondary reactions in this system. The results obtained are interpreted in terms of diffusional quenching mechanism and are compared with those obtained using different halomethanes. © 1994. Fil:Biondic, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_10106030_v77_n2-3_p149_Biondic |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The photochemical behaviour of full-aromatic β-carbolines (nor-harmane, harmane and harmine) in chloroform medium and the corresponding UV absorption and fluorescence emission spectra are discussed. Irreversible electron transfer from the singlet excited β-carboline molecule to the chloroform molecule in the transient excited charge transfer complex has been proposed as the primary photochemical process initiating the mechanism of secondary reactions in this system. The results obtained are interpreted in terms of diffusional quenching mechanism and are compared with those obtained using different halomethanes. © 1994. |
| format |
JOUR |
| author |
Biondic, M.C. Erra-Balsells, R. |
| spellingShingle |
Biondic, M.C. Erra-Balsells, R. Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| author_facet |
Biondic, M.C. Erra-Balsells, R. |
| author_sort |
Biondic, M.C. |
| title |
Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| title_short |
Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| title_full |
Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| title_fullStr |
Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| title_full_unstemmed |
Photochemical reaction of full-aromatic β-carbolines in halomethanes 2. CHCl3: Electronic spectra and kinetics |
| title_sort |
photochemical reaction of full-aromatic β-carbolines in halomethanes 2. chcl3: electronic spectra and kinetics |
| url |
http://hdl.handle.net/20.500.12110/paper_10106030_v77_n2-3_p149_Biondic |
| work_keys_str_mv |
AT biondicmc photochemicalreactionoffullaromaticbcarbolinesinhalomethanes2chcl3electronicspectraandkinetics AT errabalsellsr photochemicalreactionoffullaromaticbcarbolinesinhalomethanes2chcl3electronicspectraandkinetics |
| _version_ |
1807320073803661312 |