First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone)
Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene.
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso |
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todo:paper_14203049_v5_n3_p564_Bruttomesso2023-10-03T16:13:26Z First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) Bruttomesso, A.C. Gros, E.G. (20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene. Fil:Bruttomesso, A.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable |
spellingShingle |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable Bruttomesso, A.C. Gros, E.G. First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
topic_facet |
(20) 3beta,16beta dihydroxy 5 pregnen 20,16 carbolactone 3beta hydroxy 5 androsterone alkaloid derivative androsterone diosgenin hydroxyl group lactone sapogenin steroid unclassified drug catabolism cis isomer conference paper correlation analysis extraction fruit molecular dynamics molecular interaction molecular mechanics plant plant yield probability protein degradation protein isolation solanum vespertilio stereochemistry synthesis technique tomato vegetable |
description |
Diosgeninlactone (1), a natural product from Solanum vespertilio, was stereo-selectively synthesized in high yield from 3β-hydroxy-5-androstene. |
format |
JOUR |
author |
Bruttomesso, A.C. Gros, E.G. |
author_facet |
Bruttomesso, A.C. Gros, E.G. |
author_sort |
Bruttomesso, A.C. |
title |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
title_short |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
title_full |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
title_fullStr |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
title_full_unstemmed |
First synthesis of (20S) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
title_sort |
first synthesis of (20s) 3β,16β-dihydroxy-5-pregnen-20,16- carbolactone (diosgeninlactone) |
url |
http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p564_Bruttomesso |
work_keys_str_mv |
AT bruttomessoac firstsynthesisof20s3b16bdihydroxy5pregnen2016carbolactonediosgeninlactone AT groseg firstsynthesisof20s3b16bdihydroxy5pregnen2016carbolactonediosgeninlactone |
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