Perfluoroalkylation of alkenes and alkynes in water

Perfluoroalkylation of alkenes and alkynes was performed using thermal initiation by ACCN (1,1′-azobis(cyclohexanecarbonitrile)) in water, with good yields. The procedure is simple and more ecofriendly that most of the methods published for the synthesis of related compounds. Using water (without an...

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Detalles Bibliográficos
Autores principales: Vázquez, A.J., Nudelman, N.S.
Formato: JOUR
Materias:
Perfluoroalkylation
Radical addition
Reactions in water
Thermal initiation
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15517004_v2015_n5_p190_Vazquez
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_15517004_v2015_n5_p190_Vazquez
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spelling todo:paper_15517004_v2015_n5_p190_Vazquez2023-10-03T16:25:21Z Perfluoroalkylation of alkenes and alkynes in water Vázquez, A.J. Nudelman, N.S. Perfluoroalkylation Radical addition Reactions in water Thermal initiation Perfluoroalkylation of alkenes and alkynes was performed using thermal initiation by ACCN (1,1′-azobis(cyclohexanecarbonitrile)) in water, with good yields. The procedure is simple and more ecofriendly that most of the methods published for the synthesis of related compounds. Using water (without any cosolvent or metal catalysts), it allows the synthesis of the addition products with medium to high yields. ©ARKAT-USA, Inc. Fil:Vázquez, A.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15517004_v2015_n5_p190_Vazquez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Perfluoroalkylation
Radical addition
Reactions in water
Thermal initiation
spellingShingle Perfluoroalkylation
Radical addition
Reactions in water
Thermal initiation
Vázquez, A.J.
Nudelman, N.S.
Perfluoroalkylation of alkenes and alkynes in water
topic_facet Perfluoroalkylation
Radical addition
Reactions in water
Thermal initiation
description Perfluoroalkylation of alkenes and alkynes was performed using thermal initiation by ACCN (1,1′-azobis(cyclohexanecarbonitrile)) in water, with good yields. The procedure is simple and more ecofriendly that most of the methods published for the synthesis of related compounds. Using water (without any cosolvent or metal catalysts), it allows the synthesis of the addition products with medium to high yields. ©ARKAT-USA, Inc.
format JOUR
author Vázquez, A.J.
Nudelman, N.S.
author_facet Vázquez, A.J.
Nudelman, N.S.
author_sort Vázquez, A.J.
title Perfluoroalkylation of alkenes and alkynes in water
title_short Perfluoroalkylation of alkenes and alkynes in water
title_full Perfluoroalkylation of alkenes and alkynes in water
title_fullStr Perfluoroalkylation of alkenes and alkynes in water
title_full_unstemmed Perfluoroalkylation of alkenes and alkynes in water
title_sort perfluoroalkylation of alkenes and alkynes in water
url http://hdl.handle.net/20.500.12110/paper_15517004_v2015_n5_p190_Vazquez
work_keys_str_mv AT vazquezaj perfluoroalkylationofalkenesandalkynesinwater
AT nudelmanns perfluoroalkylationofalkenesandalkynesinwater
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