catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O} n , is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, Er III and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrog...
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| Autores principales: | , , |
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_16005368_v64_n11_pm1463_Baggio |
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todo:paper_16005368_v64_n11_pm1463_Baggio2023-10-03T16:27:44Z catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] Baggio, R. Perec, M. Garland, M.T. Tetra The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O} n , is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, Er III and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear 1:1:2 fourfold bridges [Cu⋯Cu = 2.6417 (9) Å] and of Ho2 units bridged by two 2:1:2 carboxyl-ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one 2:1:2 carboxyl-ate O atom and two hydrogen bonds with Cu⋯Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol-ecules could not be located, but the O⋯O separations for these species suggest the presence of O - H⋯O hydrogen bonds. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_16005368_v64_n11_pm1463_Baggio |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Tetra |
| spellingShingle |
Tetra Baggio, R. Perec, M. Garland, M.T. catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| topic_facet |
Tetra |
| description |
The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O} n , is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, Er III and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear 1:1:2 fourfold bridges [Cu⋯Cu = 2.6417 (9) Å] and of Ho2 units bridged by two 2:1:2 carboxyl-ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one 2:1:2 carboxyl-ate O atom and two hydrogen bonds with Cu⋯Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol-ecules could not be located, but the O⋯O separations for these species suggest the presence of O - H⋯O hydrogen bonds. |
| format |
JOUR |
| author |
Baggio, R. Perec, M. Garland, M.T. |
| author_facet |
Baggio, R. Perec, M. Garland, M.T. |
| author_sort |
Baggio, R. |
| title |
catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| title_short |
catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| title_full |
catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| title_fullStr |
catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| title_full_unstemmed |
catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| title_sort |
catena-poly[[[tetra-kis(μ-2-butenoato)dicopper(ii)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(iii)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(iii)]-μ-2-butenoato] trihydrate] |
| url |
http://hdl.handle.net/20.500.12110/paper_16005368_v64_n11_pm1463_Baggio |
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