Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide

The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give...

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Detalles Bibliográficos
Autores principales: Trápani, C., Escola, N., Doctorovich, F.
Formato: JOUR
Materias:
Nucleophilic attacks
Concentration (process)
Fourier transform infrared spectroscopy
Lithium compounds
Mixtures
Nuclear magnetic resonance spectroscopy
Phase equilibria
Stoichiometry
Ultraviolet spectroscopy
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02767333_v21_n10_p2021_Trapani
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give a strong indication that diazoates (and/or diazoic acids) are intermediates in the reactions of amines with these nitrosyl complexes.

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